Quantcast
Channel: blog化学
Viewing all articles
Browse latest Browse all 2255

スルフォキサイドによるC-H活性化: Teaching an Old Functional Group New Tricks

$
0
0
C−H Coupling Reactions Directed by Sulfoxides: Teaching an Old Functional Group New Tricks
 
 (Angew. Chemie pages 9842–9860)
 
Dr. Alexander P. Pulis and Prof. David J. Procter

Version of Record online: 13 JUL 2016 | DOI: 10.1002/anie.201601540
 
Classical sulfoxide directing groups have been given a new lease on life because of their unique ability to direct a variety of C−H couplings to form important C−C bonds.
 
イメージ 1Sulfoxide direction operates through internal coordination to a metal (directing groups), through external coordination (ligands), or via sulfoxide capture of nucleophilic or electrophilic coupling partners (sulfonium-directed).
 
イメージ 2
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
Wikipedia
 
イメージ 3
イメージ 4

Viewing all articles
Browse latest Browse all 2255

Trending Articles