分子内銅塩触媒CH・NHCoupling反応が面白い。
分子間と同じくポイントはC-H結合のActivationである。
www-gaunt.ch.cam.ac.uk/activation.sht
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We are interested in developing new inter- and intramolecular C-C bond forming reactions catalysed by transition metals. In particular, our research focuses on the activation of C-H bonds and we are investigating methods by which sp, sp2 and sp3 hybridised C-H bonds can be activated by transition metal catalysts under ambient conditions to form a diverse range of useful molecular architectures.