エステル化合物でＳｕｚｕｋｉ－ＭｉｙａｕｒａＣ－Ｃ Couplimg
Figure 1 | Esters as electrophiles in the Suzuki–Miyaura coupling.
(a) Electrophiles (R–Z) in the Suzuki–Miyaura coupling with organoboron compoundscatalysed by palladium or nickel; Z.halogen (standard), Z.N, O, S (emerging), Z.CO2Ph (esters; this work).
(b) Advantages of using esters as electrophilic coupling partners in Suzuki–Miyaura coupling.
(c) Our mechanistic blueprint of decarbonylative cross-coupling of esters and boronic acidscatalysed by nickel.